Mass analysis in islands of stability with linear quadrupoles with added octopole fields

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Mass analysis with islands of stability with linear quadrupoles incorporating higher order multipole fields.

Mass analysis with islands of stability has been investigated with three linear quadrupole mass filters: two with 4% added hexapole fields constructed with equal diameter (quadrupole 4A) and unequal diameter (quadrupole 4B) rods, and a conventional round-rod quadrupole that has apparently been slightly damaged. Islands are formed by applying auxiliary quadrupole excitation. With the Mathieu par...

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15 صفحه اول

Linear quadrupoles in mass spectrometry.

The use of linear quadrupoles in mass spectrometry as mass filters and ion guides is reviewed. Following a tutorial review of the principles of mass filter operation, methods of mass analysis are reviewed. Discussed are extensions of quadrupole mass filters to higher masses, scanning with frequency sweeps of the quadrupole waveform, operation in higher stability regions, and operation with rect...

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ژورنال

عنوان ژورنال: Journal of the American Society for Mass Spectrometry

سال: 2007

ISSN: 1044-0305,1879-1123

DOI: 10.1016/j.jasms.2007.01.002